Journal of Organometallic Chemistry p. 167 - 172 (1989)
Update date:2022-08-05
Topics:
Mitchell, Terence N.
Belt, Heinz-Joachim
(β-Trimethylstannyl)alkyldiphenylphosphines can be readily prepared by addition of diphenylphosphine to the corresponding vinyltrimethyltin Me3SnCR=CH2 under free radical conditions.In contrast, free radical hydrostannation of the corresponding phosphines Ph2PCR=CH2 is a more complex process, and is apparently of little synthetic value.The title compound can be easily oxidised by potassium permanganate to give the corresponding phosphine oxides in good yields.Hydrostannation of model alkynyldiphenylphosphines (RC<*>CPPh2, R=H, Me3Sn) occurs regiospecifically.
Contact:886 2 2541 0022
Address:8 Fl., No. 11, Sec. 1, Chung Shan North Rd., Taipei, Taiwan R.O.C.
Zhejiang kehong chemical co., ltd
Contact:0086-575-85522000
Address:xiner center RD binhai industrial zone shaoxing zhejiang province P.R.China,312073
website:http://www.konochem.com
Contact:86-29-86107037
Address:No.170 West Avenue,Xi’an 710082,China
Chengdu Cogon Bio-tech Co., Ltd.
Contact:86-28-85171192
Address:NO.52.YongFeng Rd. Chengdu,610041,P.R.China.
Jiande City Silibase Silicone New Material Manufacture Co., Ltd.
Contact:15967177856
Address:Genglou Industrial Development Area
Doi:10.1002/cmdc.201000194
(2010)Doi:10.1021/ol5034173
(2015)Doi:10.1016/0022-328X(89)87298-5
(1989)Doi:10.1021/jo101704b
(2010)Doi:10.1016/j.carres.2010.08.012
(2010)Doi:10.1002/ejoc.201300767
(2013)
