Chemical Communications p. 1772 - 1774 (2012)
Update date:2022-09-26
Topics:
Maeda, Hironori
Yamada, Shinya
Itoh, Hisanori
Hori, Yoji
We have demonstrated that a combination of enantiopure 2- diarylmethylpyrrolidines and heterogeneous Pd/BaSO4 is an efficient catalytic system for the asymmetric hydrogenation of citral, specifically, a mixture of E-citral and Z-citral in any ratio, and that citronellal is obtained with high enantioselectivity. This dual catalyst system provides a new and more economical route to l-menthol.
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