Formation of - and Paracyclophane Derivatives in Cycloaddition Reactions

DOI: 10.1021/ja00413a017

Source and publish data:

Journal of the American Chemical Society p. 6878 - 6884 (1981)

Update date:2022-09-26

Topics:

Authors:

Kataoka, Fumio

Nishida, Shinya

Tsuji, Takashi

Murakami, Masashi

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Article abstract of DOI:10.1021/ja00413a017

Reactions of tetracyclopropylethylene (1a) and cis-1,2-dicyclopropylstilbene (1b) and its trans isomer (1c) with TCNQ gave 5,6-disubstituted <10>paracyclophane-4,6-dienes (2) in 50-70percent yields.In a similar manner, 1-alkyl- or 1-phenyl substituted 1-c

Full text of DOI:10.1021/ja00413a017

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