Uebergangsmetall-Heteroallen-Komplexe. XXII. Zweikernige Cobalt- und Eisen-Komplexe mit Bis(trifluormethyl)- und Bis(ethoxycarbonyl)thioketen als Liganden

Article abstract of DOI:10.1016/0022-328X(89)88030-1

Co2(CO)8 reacts with the thioketene (CF3)2CCS to give a dinuclear compound 2 (6).Photolysis of (CF3)2CCS with Fe(CO)5 leads to two differing complexes of the type (9) and 2 (10).The dimeric thioketene (EtOOC)2CCSSCC(COOEt)2 reacts with Fe(CO)5 to give (13).The crystal structure of 9 has been determined by X-ray diffraction.