Tetrahedron Asymmetry p. 1591 - 1596 (1992)
Update date:2022-08-02
Topics:
Irrure, J.
Alonso-Alija, C.
Piniella, J. F.
Alvarez-Larena, A.
We report the synthesis of the 1,4-diol 2 (4R,5R)-α,α,α',α-2,2-hexaphenyl-4,5-dimethanol-1,3-dioxolane from dimethyl-L-tartrate and benzophenone.The X-ray and the IR structural studies on 2 show that this compound has a preferred conformation with OH --- Ph interactions which are different from related compounds.
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