Intramolecular cyclization of acetylenic homoallylic ketones mediated by the addition of stannyl radicals; a short facile pathway to α-methylene-β-substituted cyclopentanones

DOI: 10.1016/S0040-4039(01)93939-5

Source and publish data:

Tetrahedron Letters p. 7219 - 7220 (1989)

Update date:2022-08-02

Topics:

Authors:

Lee Lee

Hur Hur

Park Park

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)93939-5

α-(Stannyl)methylenecyclopentanones are obtained by tributylstannane addition reactions of acetylenic homoallylic ketones. α-Methylenecyclopentanones are produced upon destannylation.

Full text of DOI:10.1016/S0040-4039(01)93939-5

Products guided by the article

Product name:(Z)-7-Phenyl-hept-6-en-1-yn-3-one

Cas No:126976-43-0

R&D Labs maybe for 126976-43-0

Hangzhou Yingshanhua Pigment Chemicals Co.,Ltd.

Contact:+86-0150-58101658

Address:Nanyang Economic DevelopmentZong,Xiaoshan,Hangzhou,China
Shandong Dayi Chemical Co., Ltd.

website:http://www.dayi.com.cn

Contact:+86- 535-7388728. 15306386031

Address:No 1 Danya west road, Laiyang City, Shandong province
Angelisun(Chongqing) Pharmaceutical Co., LTD.

Contact:+86-23-68030926-816

Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China
Yurui(Shanghai)Chemical Co.,Ltd

Contact:0086 21-50456736

Address:No.3188 Xiupu Road,Shanghai
xujianqiang

Contact:86-21-57725962

Address:shanghai

Relevant to this article

2-Acetylpyridine thiocarbonohydrazones. Potent inactivators of herpes simplex virus ribonucleotide reductase

Doi:10.1021/jm00090a022
(1992)
Chemoenzymatic total synthesis of cryptocaryalactone natural products

Doi:10.1016/j.tetlet.2017.12.014
(2018)
Enantioselective synthesis of axially chiral 1-arylisoquinolines by rhodium-catalyzed [2+2+2] cycloaddition

Doi:10.1002/chem.201003134
(2011)
Structurally Diverse Mitochondrial Branched Chain Aminotransferase (BCATm) Leads with Varying Binding Modes Identified by Fragment Screening

Doi:10.1021/acs.jmedchem.5b01607
(2016)
Nonclassical 2,4-diamino-6-(aminomethyl)-5,6,7,8-tetrahydroquinazoline antifolates: Synthesis and biological activities

Doi:10.1021/jm00018a027
(1995)
Design and synthesis of novel isoquinoline-3-nitriles as orally bioavailable Kv1.5 antagonists for the treatment of atrial fibrillation

Doi:10.1021/jm060927v
(2006)

Article Doi