Tetrahedron Letters p. 5003 - 5006 (1986)
Update date:2022-07-31
Topics:
Cornelisse, Jan
Gilbert, Andrew
Rodwell, Paul W.
The observed specificity of meta photocycloaddition of trans 1,2-dichloroethylene to benzenoid compounds is deduced to arise from a chlorine atom induced asymmetric distortion of the reaction intermediate: thermal and photochemical isomerisations of the adducts occur by an ethenylcyclopropane-cyclopentene rearrangement and/or 1,3- and 1,5-chlorine shifts.
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