FACILE AERIAL OXIDATION OF UNSYMMETRICAL MESO-TETRAARYL PORPHYRINS WITH 3,5-DI-t-BUTYL-4-HYDROXYPHENYL (DtB4HP) AND 4-NITROPHENYL (4-NP) SUBSTITUENS.

DOI: 10.1016/S0040-4020(01)89195-X

Source and publish data:

Tetrahedron p. 7341 - 7352 (1989)

Update date:2022-08-04

Topics:

Authors:

Milgrom, Lionel R.

Mofidi, Nasrin

Harriman, Anthony

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Article abstract of DOI:10.1016/S0040-4020(01)89195-X

Porphyrins unsymmetrically substituted with 3,5-di-t-butyl-4-hydroxyphenyl (DtB4HP) and 4-nitrophenyl (4-NP) groups, have been synthesised and characterised.Their aerial oxydation in basified dichloromethane solution has been studied, using u.v.-visible spectroscopy, and compared with their half-wave potentials (E⁰) obtained from cyclic voltammetry.

Full text of DOI:10.1016/S0040-4020(01)89195-X

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