Stereoselective α-alkylation of carbonyl compounds using tricarbonylchromium-complexed benzyl acetates

DOI: 10.1016/0022-328X(90)85221-J

Source and publish data:

Journal of Organometallic Chemistry p. 121 - 128 (1990)

Update date:2022-08-05

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Authors:

Reetz, M. T.

Sauerwald, M.

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Article abstract of DOI:10.1016/0022-328X(90)85221-J

Secondary benzyl acetates complexed by Cr(CO)3 react 100percent stereoselectively with enolsilanes in the presence of ZnCl2 in a process which amounts to α-alkylation of carbonyl compounds.

Full text of DOI:10.1016/0022-328X(90)85221-J

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