Stereoselective α-alkylation of carbonyl compounds using tricarbonylchromium-complexed benzyl acetates

DOI: 10.1016/0022-328X(90)85221-J

Source and publish data:

Journal of Organometallic Chemistry p. 121 - 128 (1990)

Update date:2022-08-05

Topics:

Authors:

Reetz, M. T.

Sauerwald, M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(90)85221-J

Secondary benzyl acetates complexed by Cr(CO)3 react 100percent stereoselectively with enolsilanes in the presence of ZnCl2 in a process which amounts to α-alkylation of carbonyl compounds.

Full text of DOI:10.1016/0022-328X(90)85221-J

Products guided by the article

Product name:rac-2-(1-phenylethyl)cyclohexanonetricarbonylchromium

Cas No:127852-52-2

R&D Labs maybe for 127852-52-2

Hotechem Shanghai Co., Ltd

Contact:13120882795；+86-21-34621078;+86-021-31122318

Address:Suite 2,No.2715 Longwu Road
XZL BIO-TECHNOLOGY CO., LTD.

Contact:0086 533 2282832

Address:Zibo，Shandong
Tianjin Tensing Fine Chemical Research Develop Centre

Contact:86-022-23718576,13032267585

Address:2-2-201,13 Guiyuan road,Huayuan Industry district,Tianjin,china
Shanghai Yuking Water Soluble Material Tech Co., Ltd

Contact:86-21-68286299

Address:4F, 13B, No. 600, South Xinyuan Road 201306, Shanghai, China
NANCHANG QINZHI SCI&TEC.CO.,LTD(expird)

Contact:+86-13687004106

Address:Hero South Road,Hero Zone,Nanchang,Jiangxi,China

Relevant to this article

IBX works efficiently under solvent free conditions in ball milling

Doi:10.1039/c4ra00415a
(2014)
Preparation of 2-alkylidene-substituted 1,3,4,5-tetramethylimidazolines and their reactivity towards Rh^I Complexes and B(C₆F ₅)₃

Doi:10.1002/ejic.201201516
(2013)
CHARACTERISTICS OF HETEROCYCLIZATION OF TRIKETONES OF THE 2-(3-OXOPROPYL)CYCLOHEXANE-1,3-DIONE SERIES WITH HYDROXYLAMINE HYDROCHLORIDE

Doi:10.1007/BF00499412
(1990)
Influence of mixed thiolate/thioether versus dithiolate coordination on the accessibility of the uncommon +I and+III oxidation states for the nickel ion: An experimental and computational study

Doi:10.1021/ic200063d
(2011)
Reaction of 3,4-dihydro-2H-thiopyran with phenylhydrazines. Synthesis of homothiotryptophols

Doi:10.1007/BF00470691
(1990)
Synthesis and Central Nervous System Actions of Thyrotropin-Releasing Hormone Analogues Containing a Dihydroorotic Acid Moiety

Doi:10.1021/jm00170a014
(1990)

Article Doi