First preparation of allyl vanadium reagents in a mixed solvent of THF and HMPA (HMPA = hexamethylphosphoric triamide) and their application to allylation of carbonyl compounds

DOI: 10.1016/0040-4039(96)01579-1

Source and publish data:

Tetrahedron Letters p. 7083 - 7086 (1996)

Update date:2022-08-03

Topics:

Authors:

Kataoka, Yasutaka

Makihira, Isamu

Tani, Kazuhide

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Article abstract of DOI:10.1016/0040-4039(96)01579-1

Allylation of carbonyl compounds with allyl bromide mediated by a vanadium(II) complex in a mixed solvent of THF and HMPA (HMPA = hexamethylphosphoric triamide) has been accomplished. Coordination of HMPA to a vanadium metal is essential for the stabilization of the allyl vanadium species.

Full text of DOI:10.1016/0040-4039(96)01579-1

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