Alkyne Insertion Reactions of Metal-Carbenes Derived from Enynyl α-Diazo Ketones C(CH2)n-2CH=CH2>

DOI: 10.1021/jo00302a010

Source and publish data:

Journal of Organic Chemistry p. 4518 - 4520 (1990)

Update date:2022-08-04

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Authors:

Hoye, Thomas R.

Dinsmore, Christopher J.

Johnson, Douglas S.

Korkowski, Paul F.

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Article abstract of DOI:10.1021/jo00302a010

The title substrates react with a variety of metal catalysts to give metal-dependent product arrays (including tricyclic cyclopropanes and others formally arising from the vinylogous α-keto carbene 3 shown in scheme I) of both synthetic and mechanistic in

Full text of DOI:10.1021/jo00302a010

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