Chemistry Letters p. 1739 - 1742 (1986)
Update date:2022-07-30
Topics:
Suzuki, Michiyo
Matsumoto, Teruyo
Ohsaki, Masako
Kimura, Yoshikazu
Terashima, Shiro
The title compounds were effectively synthesized by chemoselective reduction of (R)-methyl 2,5,12-trihydroxy-6,11-dioxo-1,2,3,4-tetrahydronaphthacene-2-carboxylate to the corresponding (R)-alcohol with lithium tri-t-butoxyaluminium hydride, followed by stereoselective C7α-hydroxylation (the anthracycline numbering) and urethane formation.
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Doi:10.1021/ja00038a012
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