Organometallic peptide NHC complexes of CpRh(III) and arene Ru(II) moieties from l-thiazolylalanine

DOI: 10.1016/j.jorganchem.2010.12.044

Source and publish data:

Journal of Organometallic Chemistry p. 1018 - 1022 (2011)

Update date:2022-07-29

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Authors:

Lemke, Jessica

Metzler-Nolte, Nils

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Article abstract of DOI:10.1016/j.jorganchem.2010.12.044

The 3-ethyl thiazolium peptide salts Boc-Thia-Leu-OMe and Boc-Thia-Leu-Phe-OMe based on the unnatural amino acid thiazolylalanine (Thia) have been prepared. After deprotonation, they reacted rapidly via the silver carbene transfer reaction with [RhCpCl₂]₂ and [Ru(p-cymene)Cl₂]₂ to yield the corresponding thiazole-based carbene complexes 7-10 in acceptable yield. All new compounds were characterized by multinuclear NMR spectroscopy, mass spectrometry, and elemental analysis. These complexes constitute the first examples of thiazolylalanine-2-ylidene metal bioconjugates.

Full text of DOI:10.1016/j.jorganchem.2010.12.044

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