Unexpected formation of optically active 4-substituted 5-hydroxy-γ- lactams by organocatalyzed reaction of 3-substituted cyclobutanones with nitrosobenzene

DOI: 10.1055/s-0030-1259084

Source and publish data:

Synlett p. 89 - 93 (2011)

Update date:2022-07-29

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Authors:

Capitta, Francesca

Frongia, Angelo

Ollivier, Jean

Piras, Pier Paolo

Secci, Francesco

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Article abstract of DOI:10.1055/s-0030-1259084

An organocatalyzed enantioselective desymmetrization reaction for converting 3-substituted cyclobutanones into 4-substituted 5-hydroxy-γ- lactams is presented. This involves a ring-expanding O-nitroso aldol-cyclization domino sequence. This synthetic prot

Full text of DOI:10.1055/s-0030-1259084

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