Stereoselective formation of allylic sulfides via two sequential [3,3]-sigmatropic rearrangements of allylic xanthates and its mechanistic aspects

DOI: 10.1248/cpb.38.619

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 619 - 624 (1990)

Update date:2022-08-04

Topics:

Authors:

Harano Harano

Ohizumi Ohizumi

Misaka Misaka

Yamashiro

Hisano Hisano

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.38.619

O-(2-Alkenyl) S-alkyl dithiocarbonates (allylic xanthates) were pyrolyzed to give 2-alkenyl alkyl sulfides (allylic sulfides) via the corresponding allylically isomeric S-(2-alkenyl) S-alkyl dithiocarbonates. The reaction follows the first-order rate law

Full text of DOI:10.1248/cpb.38.619

NII-Electronic Library Service

Products guided by the article

Product name:S-(1-phenylcrotyl) S-methyl dithiocarbonate

Cas No:128800-01-1

R&D Labs maybe for 128800-01-1

WD Silicone Co., Ltd

Contact:+86-27-87204219, +86-27-87215023

Address:2402, HuiGu Space-time Building, 8 Forest Road, East Lake Hi-Tech Development Zone
Chengdu D-Innovation Pharmaceutical Co., Ltd

Contact:86-28-85105536

Address:1001, B6, No.88 Keyuan South Road, Chengdu Hi-Tech Zone
CHANGYI CITY FENGRUN FINE CHEMICAL CO.,LTD

website:http://www.fengrunhuagong.com

Contact:+86-536-7869976

Address:Changyi Coastal Economic Development Zone
Lanzhou huibang biological chemical technology Co., LTD

Contact:0931-7843964

Address:NO.2011,Yannan Road,Chengguan,
Huangshan Violet Biological Technology Co., Ltd

Contact:+86-559-2335676

Address:16-201 JinShanYuan,JiangNan New City,TunXi District,HuangShan City,AnHui Province,China

Relevant to this article

Cyclization of aromatic dithioic esters: Synthesis of 1,3-benzodithioles

Doi:10.1016/0040-4039(90)80087-3
(1990)
Organocatalytic synthesis of multiple substituted b[4.4.0]decalin system

Doi:10.1021/ol200424x
(2011)
Structure and reactivity of acetylene complexes of bis(imino)pyridine ruthenium(0)

Doi:10.1021/om100953g
(2011)
The synthesis and SAR of novel diarylsulfone 11β-HSD1 inhibitors

Doi:10.1016/j.bmcl.2010.09.097
(2010)
Synthesis of new 3,5-disubstituted isoxazoles with specific anti-group B rhinovirus activity in vitro

Doi:10.1016/0223-5234(93)90025-A
(1993)
A cephalosporin-chemiluminescent conjugate increases beta-lactamase detection sensitivity by four orders of magnitude

Doi:10.1039/c9cc09498a
(2020)

Article Doi