Stereoselective formation of allylic sulfides via two sequential [3,3]-sigmatropic rearrangements of allylic xanthates and its mechanistic aspects

DOI: 10.1248/cpb.38.619

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 619 - 624 (1990)

Update date:2022-08-04

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Authors:

Harano Harano

Ohizumi Ohizumi

Misaka Misaka

Yamashiro

Hisano Hisano

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Article abstract of DOI:10.1248/cpb.38.619

O-(2-Alkenyl) S-alkyl dithiocarbonates (allylic xanthates) were pyrolyzed to give 2-alkenyl alkyl sulfides (allylic sulfides) via the corresponding allylically isomeric S-(2-alkenyl) S-alkyl dithiocarbonates. The reaction follows the first-order rate law

Full text of DOI:10.1248/cpb.38.619

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