A Two-Step Conversion of Carbonyl Compounds into Functionalized Five- and Six-Membered Ring Thioethers via Intramolecular Cycloaddition

DOI: 10.1021/jo00307a023

Source and publish data:

Journal of Organic Chemistry p. 5505 - 5510 (1990)

Update date:2022-07-29

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Authors:

Hassner, Alfred

Dehaen, Wim

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Article abstract of DOI:10.1021/jo00307a023

Reaction of aldehydes or ketones with nitromethane in the presence of unsaturated thiols led directly to unsaturated nitro sulfides 7, 12, 14, or 19.These compounds were converted by intramolecular nitrile oxide-olefin cycloaddition to tetrahydrothiopheno

Full text of DOI:10.1021/jo00307a023

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