A Novel Reaction of Thiirane Cation Radicals in Solution: the Formation of 5,6-Diphenyl-1,2,3,4-tetrathianes through Trisulphurated Thiirane Cation Radical Intermediates

DOI: 10.1039/c39900000827

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 827 - 829 (1990)

Update date:2022-08-02

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Authors:

Kamata, Masaki

Murayama, Kazuyuki

Suzuki, Takanori

Miyashi, Tsutomu

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Article abstract of DOI:10.1039/c39900000827

A novel reaction of thiirane cation radicals to form cis- and trans-5,6-diphenyl-1,2,3,4-tetrathianes took place when cis- and trans-2,3-diphenylthiiranes were mixed with a catalytic amount of tris(p-bromophenyl)aminium hexachloroantimonate (3) in dichloromethane.

Full text of DOI:10.1039/c39900000827

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