Chemistry of Heterocyclic Compounds p. 887 - 891 (1988)
Update date:2022-08-05
Topics:
Prostakov, N. S.
Kuznetsov, V. V.
Gaivoronskaya, L. A.
Murugova, L. A.
Stashenko, E. E.
Zakharov, P. I.
N-Aryl(aralkyl)-N-(4-piperidinyl)benzylamines have been prepared from γ-N-(arylamino)piperidines using the Wallach reaction.Carbonyl-containing compounds have been detected as impurities in these products using mass spectrometry.A possible mechanism is discussed for the Wallach reaction, based on the structures of the secondary amine starting materials used in this study.
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Doi:10.1016/S0040-4039(00)94672-0
(1990)Doi:10.1021/acs.joc.8b02487
(2019)Doi:10.1016/j.jorganchem.2014.05.040
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