CHEMICAL SYNTHESIS OF DIMER RIBONUCLEOTIDES CONTAINING INTERNUCLEOTIDIC PHOSPHORODITHIOATE LINKAGES

DOI: 10.1016/S0040-4039(00)94661-6

Source and publish data:

Tetrahedron Letters p. 911 - 914 (1990)

Update date:2022-08-02

Topics: Chemical Synthesis

Authors:

Petersen, Kenneth H.

Nielsen, John

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Article abstract of DOI:10.1016/S0040-4039(00)94661-6

Ribonucleosides, chlorobis(amino)phosphines and thiols react via phosphorothioamidites to form phosphorothioites.Oxidation with sulphur gives ribonucleoside phosphorodithioate triesters which after deprotection yields the phosphorodithioate ribonucleoside

Full text of DOI:10.1016/S0040-4039(00)94661-6

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