Tetrahedron Letters p. 1409 - 1412 (1990)
Update date:2022-08-02
Topics:
De Cusati, Paul F.
Olofson
The TiCl4-catalyzed addition of the title reactants to vinyl ketones regio- and stereospecifically yields cis-disubs, cyclohexenes which add RMgX stereospecifically to the ketone. A final product in this sequence is the intensely sweet sesquiterpene, hernandulcin.
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(1966)Doi:10.1039/C39900000984
(1990)
