Tetrahedron Letters p. 1409 - 1412 (1990)
Update date:2022-08-02
Topics:
De Cusati, Paul F.
Olofson
The TiCl4-catalyzed addition of the title reactants to vinyl ketones regio- and stereospecifically yields cis-disubs, cyclohexenes which add RMgX stereospecifically to the ketone. A final product in this sequence is the intensely sweet sesquiterpene, hernandulcin.
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Doi:10.1016/0223-5234(90)90207-J
(1990)Doi:10.1039/c39900000790
(1990)Doi:10.1021/jm2001019
(2011)Doi:10.1016/j.ica.2011.01.008
(2011)Doi:10.1016/S0022-328X(00)83353-7
(1966)Doi:10.1039/C39900000984
(1990)
