Journal of the Chemical Society. Perkin transactions I p. 1281 - 1287 (1990)
Update date:2022-07-29
Topics:
Leroy, Jacques
Fischer, Nathalie
Wakselman, Claude
Two 'unnatural' derivatives of shikimic acids, cis- and trans-6-trifluoromethylshikimic acid, have been synthesized in their racemic forms via the base-promoted opening of furan Diels-Alder adducts bearing a CF3 group.The relative stereochemistry of the trans-diastereoisomer has been confirmed by an X-ray analysis of its t-butyl ester.
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