Stereoselective Free-Radical Cyclization on a Sugar Template The Suphonyl Radical as a Synthetic Tool for Functionalized Glycosides

DOI: 10.1016/S0040-4039(00)94437-X

Source and publish data:

Tetrahedron Letters p. 3541 - 3544 (1990)

Update date:2022-07-29

Topics: Stereoselective Sulfonyl Radical

Authors:

Nouguier, Robert

Lesueur, Catherine

Riggi, Enzo de

Bertrand, Michele Paula

Virgili, Albert

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Article abstract of DOI:10.1016/S0040-4039(00)94437-X

The addition of a sulphonyl radical to the external double bond of an allyl glycal generates a pro-chiral carbon radical which adds to the glycal double bond with a high diastereoselectivity.Through three consecutive radical steps, the configurations of three new asymmetric centers are controlled.

Full text of DOI:10.1016/S0040-4039(00)94437-X

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