Unexpected Nitrogen-Oxygen Exchange Reactions in Cyclic Metallaphosphazenes: Synthesis and X-Ray Crystal Structures of (formula), (formula), and (formula)

DOI: 10.1039/DT9900002387

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2387 - 2392 (1990)

Update date:2022-08-04

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Authors:

Rietzel, Mathias

Roesky, Herbert W.

Katti, Kattesh V.

Schmidt, Hans-Georg

Herbst-Irmer, Regine

et al. et al.

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Article abstract of DOI:10.1039/DT9900002387

The reaction of (formula) with Ph3SiOH and Bu^tOH lead not to the expected substitution products but to exchange and rearrangement reactions in which the nitrogen atoms which co-ordinate molybdenum are replaced by oxygen.The crystal structures o

Full text of DOI:10.1039/DT9900002387

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