SYNTHESIS AND REACTIVITY OF PROTECTED β-BROMO α-IMINOACIDS; A CONVENIENT ROUTE TO STRUCTURALLY DIVERSIFIED AMINOACIDS.

DOI: 10.1016/S0040-4039(00)97458-6

Source and publish data:

Tetrahedron Letters p. 3739 - 3742 (1990)

Update date:2022-08-05

Topics: Synthesis Cyclization Reactions Substitution Reactions

Authors:

Danion-Bougot, R.

Danion, D.

Francis, G.

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Article abstract of DOI:10.1016/S0040-4039(00)97458-6

The title compounds are obtained by N-bromosuccinimide oxidation of protected didehydroaminoacids.Additions of the imino group are readily performed with borohydride, Grignard reagents or other nucleophiles.Heterocyclic aminoacids are available by subsequent displacement of bromine.

Full text of DOI:10.1016/S0040-4039(00)97458-6

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