Generalization, Alteration, and Enhancement of the Stereoselectivity in the Cieplak-Mode Reductions of 4-Alkoxy(or Silyloxy)cyclohexanones

DOI: 10.1246/cl.1990.1507

Source and publish data:

Chemistry Letters p. 1507 - 1510 (1990)

Update date:2022-08-02

Topics:

Authors:

Nagao, Yoshimitsu

Goto, Michimasa

Ochiai, Masahito

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Article abstract of DOI:10.1246/cl.1990.1507

Reductions of 4-alkoxy(or silyloxy)cyclohexanones with LiAlH4, AlH(i-Bu)2, and Li(s-Bu)3BH afforded the correponding cis alcohols in 73-80percent selectivities.Similar reduction of 4-benzyloxy- and 4-t-butyldiphenylsilyloxy-cyclohexanones with AlH(i-Bu)2

Full text of DOI:10.1246/cl.1990.1507

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