Tetrahedron Asymmetry p. 319 - 328 (1990)
Update date:2022-08-02
Topics:
Morales, Ezequiel Q.
Vazquez, Jesus T.
Martin, Julio D.
The kinetically controlled electrophilic additions to (Z,Z)-1-hydroxy-cyclonona-2,6-diene and to (Z)-threo-1-hydroxy-2,3-epoxy-6-cyclononene are studied.The stereoselectivity of these reactions can be explained by the conformational preferences of the cyclononyl systems, which are revealed by the CD exciton chirality methodology and molecular mechanics calculations.An absolute configurational study is also included.
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Doi:10.1021/jo010010y
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