Journal of Organic Chemistry p. 5603 - 5613 (2019)
Update date:2022-08-02
Topics:
Nimnual, Phongprapan
Tummatorn, Jumreang
Boekfa, Bundet
Thongsornkleeb, Charnsak
Ruchirawat, Somsak
Piyachat, Pawida
Punjajom, Kunlayanee
A novel synthetic approach for the synthesis of 5-aminotetrazoles has been developed by employing simple ketones as substrates. This methodology involved the N2-extrusion/aryl migration of azido complexes as the key step for the in situ generation of carbodiimidium ion, which could further react with hydrazoic acid and cyclize intramolecularly to provide 5-aminotetrazoles in good to excellent yields. In addition, the regioselectivity of the reaction was studied and rationalized by density functional theory calculations.
View MoreChangzhou Litong Chemical Co., Ltd.
website:http://www.litonchem.com/
Contact:+86-519-86301238
Address:Laoba Rd, Hutang town Changzhou Jiangsu
Suzhou Tianma Specialty Chemicals Co.,Ltd
Contact:+86-512-68090577
Address:#199, Huayuan Rd, Mudu, Suzhou, Jiangsu, CHINA
TIANJIN GST CHEMICAL TECHNOLOGY CO., LTD
Contact:+86-22-25210964
Address:Room. 208, No. -12-C, No. 13, Xinbei Road, Tanggu District, New Haixin Area, Tianjin City, China
Changzhou naidechemical Co.Ltd
Contact:+86-519-82589807
Address:NO.25,Houyang street,Jintan,Changzhou City
Cerametek Materials(ShenZhen)Co., Ltd.
Contact:+86-755-2324.2554
Address:A3-#9, YongChuan Street, Suite 501
Doi:10.1134/S107036321103025X
(2011)Doi:10.1080/14756366.2019.1681988
(2020)Doi:10.24820/ark.5550190.p010.618
(2018)Doi:10.1021/acs.orglett.5b03685
(2016)Doi:10.3987/COM-16-13515
(2016)Doi:10.1021/jo00081a007
(1994)