Organotransition metal substituted primary phosphines: osmium phosphido (PH2) complexes

DOI: 10.1016/0022-328X(90)80204-D

Source and publish data:

Journal of Organometallic Chemistry p. 243 - 285 (1990)

Update date:2022-08-05

Topics:

Authors:

Bohle, D. Scott

Clark, George R.

Rickard, Clifton E.F.

Roper, Warren R.

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Article abstract of DOI:10.1016/0022-328X(90)80204-D

Stable osmium phosphido complexes, Os(η²-chelate)(PH2)(CO)(PPh3)2, (chelate = acetate, N,N-dimethyldithiocarbamate, acetylacetonate, or nitrite) have been prepared by treating ClO4 with sodium acetate, sodium N,N-di

Full text of DOI:10.1016/0022-328X(90)80204-D

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Product name:osmium(η1-OC(O)CH3)(PH{C(O)CMe3})(CO)2(PPh3)2

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