Cyclometallated compounds VI. Cyclopalladation of 2-phenylpyrimidines with pendant pyrazole donors

DOI: 10.1016/0022-328X(90)85300-N

Source and publish data:

Journal of Organometallic Chemistry p. 375 - 381 (1990)

Update date:2022-09-26

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Authors:

Caygill, Graham B.

Steel, Peter

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Article abstract of DOI:10.1016/0022-328X(90)85300-N

The use of pendant pyrazole groups to induce double cyclopalladation of 2-phenylpyrimidines has been investigated. 4,6-Bis(pyrazol-1-yl)-2-phenylpyrimidine undergoes monocyclopalladation only, whilst 4-methyl-2-phenyl-6(pyrazol-1-ylmethyl)pyrimidine react

Full text of DOI:10.1016/0022-328X(90)85300-N

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