Journal of Organic Chemistry p. 487 - 489 (1991)
Update date:2022-08-02
Topics:
Kondo, Teruyuki
Mukai, Takeshi
Watanabe, Yoshihisa
Certain ruthenium complexes show high catalytic activity in the synthesis of α,β-unsaturated ketones from primary alcohols and allylic acetates.Here, ?-allylruthenium intermediates apparently operate as nucleophiles rather than as electrophiles.
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