ELECTRON TRANSFER FREE RADICAL MECHANISM IN THE REACTIONS OF ARENEDIAZONIUM CATIONS WITH GRIGNARD REAGENTS

DOI: 10.1016/0040-4039(82)80161-5

Source and publish data:

Tetrahedron Letters p. 5475 - 5478 (1982)

Update date:2022-08-04

Topics:

Authors:

Singh, P. R.

Khanna, R. K.

Jayaraman, B.

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Article abstract of DOI:10.1016/0040-4039(82)80161-5

The major pathway in the reactions of arenediazonium cations with certain Grignard reagents is found to involve an electron transfer from the latter to the ?-system of the former reactant and radicals are the immediate precursors of the final products.

Full text of DOI:10.1016/0040-4039(82)80161-5

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