A new ring expansion for a chiral hexahydroazulene skeleton possessing an angular methyl group

DOI: 10.1021/jo201153h

Source and publish data:

Journal of Organic Chemistry p. 6942 - 6945 (2011)

Update date:2022-07-29

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Authors:

Adachi, Masaatsu

Komada, Takema

Nishikawa, Toshio

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Article abstract of DOI:10.1021/jo201153h

A new synthetic route for a pseudoguaiane ring system is described. The synthesis features an Ireland-Claisen rearrangement for constructing the trans-fused ring system, followed by a new ring expansion to yield a bicyclo[5.3.0]decane ring system possessi

Full text of DOI:10.1021/jo201153h

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