2,4,6-Trifluorophenyl gold(I) and gold(III) complexes

Article abstract of DOI:10.1016/0022-328X(90)85199-9

Displacement of tetrahydrothiophen (tht) from AuR(tht) (R = 2,4,6-C6F3H2) by anionic ligands gives ^-, which reacts with AgClO4 or AgR to give 4, ^- or x.Neutral , anionic <(NBu4) or (NBu4)> or cationic ClO4> gold(III) complexes are obtained by displacement of the ether ligands of AuR3(OEt2), AuR2Cl(OEt2) or ClO4.