2,4,6-Trifluorophenyl gold(I) and gold(III) complexes

DOI: 10.1016/0022-328X(90)85199-9

Source and publish data:

Journal of Organometallic Chemistry p. 121 - 128 (1990)

Update date:2022-08-02

Topics:

Authors:

Laguna, Antonio

Laguna, Mariano

Jimenez, Josefina

Fumanal, Antonio J.

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Article abstract of DOI:10.1016/0022-328X(90)85199-9

Displacement of tetrahydrothiophen (tht) from AuR(tht) (R = 2,4,6-C6F3H2) by anionic ligands gives ^-, which reacts with AgClO4 or AgR to give 4, ^- or x.Neutral , anionic <(NBu4) or (NBu4)> or cationic ClO4> gold(III) complexes are obtained by displacement of the ether ligands of AuR3(OEt2), AuR2Cl(OEt2) or ClO4.

Full text of DOI:10.1016/0022-328X(90)85199-9

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