Novel and Selective Enzymatic Hydrolysis of γ-Esters of Dimethyl α-Dehydroglutamate with α-Chymotrypsin A

DOI: 10.1246/cl.1990.2089

Source and publish data:

Chemistry Letters p. 2089 - 2090 (1990)

Update date:2022-08-03

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Authors:

Shin, Chung-gi

Seki, Masashi

Takahashi, Nobuyuki

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Article abstract of DOI:10.1246/cl.1990.2089

Selective enzymatic hydrolysis of γ-ester of Cbz-ΔGlu(OMe)-OMe with α-chymotrypsin at pH 9 was readily achieved to give the corresponding α-half ester (Cbz-ΔGlu-OMe) along with a small amount of Cbz-ΔGlu(OMe)-OH and Cbz-ΔGlu-OH.

Full text of DOI:10.1246/cl.1990.2089

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