Tetrahedron Letters p. 6903 - 6906 (1990)
Update date:2022-09-26
Topics:
Subhas Bose
Thurston, David E.
A new efficient method for the cleavage of benzyl carbamates (CBZ protective groups) is described that involves a hard acid (BF3·OEt2) - soft nucleophile (EtSH) system. Unlike other available methods, this combination avoids the reduction of olefins, acetylenes, imines, halides and nitro groups, or the possibility of carboxylic ester hydrolysis.
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Doi:10.1007/BF00509709
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(2017)Doi:10.1039/b608979h
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(2011)Doi:10.1021/acs.orglett.5b01128
(2015)
