Synthesis of the η1-phosphaalkyne complex trans-CBut)(dppe)2> and its conversion into a η1-fluorophosphaalkene complex. Crystal structure of trans-t)(dppe)2>

DOI: 10.1016/0022-328X(91)83074-E

Source and publish data:

Journal of Organometallic Chemistry p. C23 - C26 (1991)

Update date:2022-08-02

Topics:

Authors:

Hitchcock, Peter B.

Lemos, M. Amelia N. D. A.

Meidine, Mohamed F.

Nixon, John F.

Pombeiro, Armando J. L.

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Article abstract of DOI:10.1016/0022-328X(91)83074-E

The first example of the transformation of an η¹-ligated phosphaalkyne metal complex to an η¹-phospaalkene complex is reported.

Full text of DOI:10.1016/0022-328X(91)83074-E

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Product name:trans-{FeH(η1-PFCH(tBu))(dppe)2}{FeCl2F2}

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