Tetrahedron Letters p. 8245 - 8248 (1997)
Update date:2022-09-26
Topics:
Hulme, Alison N.
Howells, Garnet E.
Studies towards the synthesis of the marine metabolite octalactin A 1, are described. Key steps in this strategy include an anti aldol reaction to set the C(r)C(s) stereochemistry, Horner Wadsworth Emmons coupling to give the trisubstituted E-double bond and a novel samarium-mediated cyclisation reaction.
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