Tetrahedron Letters p. 743 - 746 (1991)
Update date:2022-08-04
Topics:
Kuenzer, Hermann
Sauer, Gerhard
Wiechert, Rudolf
Steroidal olefins 1 and 3 undergo dimethylaluminum chloride-mediated Prins reactions with paraformaldehyde to furnish homoallylic alcohols 4 and 16 as major products. These ene reaction-type intermediates are converted into 6 and 17 by hydroxyl group-assi
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