Journal of Organic Chemistry p. 2900 - 2907 (1991)
Update date:2022-08-05
Topics:
Fisher, Matthew J.
Chow, Ken
Villalobos, Anabella
Danishefsky, Samuel J.
It has been deduced from a series of transformations that formation of a tetrahedral intermediate at C9 in FK-506 occasions fragmentation of the C9-C10 bond by a retro-Claisen-like pathway or the C9-C8 bond by a benzilic acid type rearrangement.Reduction
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