EFFECT OF THE CATION IN THE REGIOSELECTIVITY CONTROL IN REACTIONS OF 3,3-DICHLOROALLYL METALS WITH SUBSTITUTED BENZALDEHYDES

DOI: 10.1016/S0040-4020(01)86424-3

Source and publish data:

Tetrahedron p. 1485 - 1494 (1991)

Update date:2022-08-05

Topics:

Authors:

Canepa, Carlo

Cobianco, Sandra

Degani, Iacopo

Gatti, Antonella

Venturello, Paolo

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Article abstract of DOI:10.1016/S0040-4020(01)86424-3

gem-Dichloroallyl-lithium and gem-dichloroallyl-potassium produced respectively upon treatment of 3,3-dichloropropene with lithium diisopropylamide alone or in the presence of potassium tert-butoxide, show opposite regioselectivity in the reactions with substituted benzaldehydes.

Full text of DOI:10.1016/S0040-4020(01)86424-3

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