EFFECT OF THE CATION IN THE REGIOSELECTIVITY CONTROL IN REACTIONS OF 3,3-DICHLOROALLYL METALS WITH SUBSTITUTED BENZALDEHYDES

DOI: 10.1016/S0040-4020(01)86424-3

Source and publish data:

Tetrahedron p. 1485 - 1494 (1991)

Update date:2022-08-05

Topics:

Authors:

Canepa, Carlo

Cobianco, Sandra

Degani, Iacopo

Gatti, Antonella

Venturello, Paolo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)86424-3

gem-Dichloroallyl-lithium and gem-dichloroallyl-potassium produced respectively upon treatment of 3,3-dichloropropene with lithium diisopropylamide alone or in the presence of potassium tert-butoxide, show opposite regioselectivity in the reactions with substituted benzaldehydes.

Full text of DOI:10.1016/S0040-4020(01)86424-3

Products guided by the article

Product name:(4,4-Dichloro-1-phenyl-but-3-enyloxy)-trimethyl-silane

Cas No:133617-00-2

R&D Labs maybe for 133617-00-2

Changsha Botaniex Inc.

Contact:(86) 731 88718666

Address:Room 1222, Unit 4, Building B, Shangcheng, No.47, Kaiyuan East Road.
Shanghai Gsyn Chemical Co.,Ltd.

Contact:86-021-67158290

Address:86-021-67158291
KangZhiYuan Pharmaceutical Company Limited

Contact:(Sabrina)86-20-85273232

Address:4th floor, building B, Dadi industry zone, Tangxia, Tianhe, Guangzhou, China
JIANGXI ZHANGFENG CHEMICAL CO., LTD.

Contact:+86-0799-3413066

Address:Xiyuan village, Xiabu Town, Xiangdong District
Shandong Jusage Technology Co.,Ltd.

Contact:86-13406130167

Address:No.20,North Ride No.9 Road, Guangrao Economic Development Zone, Shandong Province

Relevant to this article

ZrCl ₄-catalyzed synthesis of β-aminosulfides from aziridines and thiols

Doi:10.1080/00397911.2011.553698
(2012)
An acid-promoted novel skeletal rearrangement initiated by intramolecular ipso-Friedel-Crafts-type addition to 3-alkylidene indolenium cations

Doi:10.1039/c2cc31699d
(2012)
Ligand-stabilized [P₄]²⁺ cations

Doi:10.1002/anie.201109010
(2012)
Preferred Conformation of C-Glykosides. 9. Conformational Analysis of 1,4-Linked Carbon Disaccharides

Doi:10.1021/jo00028a018
(1992)
Preparation of Activated Imines and Their Condensation with Allylstannanes: Stereoselective Synthesis of 1,2-Amino Alcohols

Doi:10.1021/jo00281a008
(1989)
Comparative study on ortho-C-H vs ortho-C-X (X = C, Cl, S) bond activation in ortho-C_aromatic-N bond fusion in substituted anilines using ruthenium(II) mediators: Isolation and characterization of unusual Ru ₂ complexes

Doi:10.1021/om300241y
(2012)

Article Doi