Journal of the American Chemical Society p. 4278 - 4281 (1991)
Update date:2022-08-03
Topics:
Zhang
Wagenseller
Conlin, Amcnd R. T.
We have reinvestigated the report that dimesitylsilylene adds nonstereospecifically to cis- and trans-2-butene. Stereospecific addition of dimesitylsilylene to cis- and trans-2-pentenes and -4-octenes produced the corresponding siliranes. A photoisomerization pathway is also reported for these siliranes. A probable explanation for the earlier and spurious interpretation is given.
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