Addition of Dimesitylsilylene to Olefins. A Reinvestigation

DOI: 10.1021/ja00011a034

Source and publish data:

Journal of the American Chemical Society p. 4278 - 4281 (1991)

Update date:2022-08-03

Topics:

Authors:

Zhang Zhang

Wagenseller

Conlin, Amcnd R. T.

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Article abstract of DOI:10.1021/ja00011a034

We have reinvestigated the report that dimesitylsilylene adds nonstereospecifically to cis- and trans-2-butene. Stereospecific addition of dimesitylsilylene to cis- and trans-2-pentenes and -4-octenes produced the corresponding siliranes. A photoisomerization pathway is also reported for these siliranes. A probable explanation for the earlier and spurious interpretation is given.

Full text of DOI:10.1021/ja00011a034

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