Journal of the Chemical Society, Dalton Transactions p. 299 - 306 (1991)
Update date:2022-08-03
Topics:
Karthikeyan, Sakthivel
Krishnamurthy, Setharampattu S.
The aryloxy(alkoxy)cyclotriphosphazenes N3P3(OR)6-n(OC6H4Me-p)n (R = Me, n = 1 - 3; R = Et or CH2Ph, n = 3) rearrange on heating to give trioxocyclotriphosphazanes; the di- and mono-methoxy derivatives, N3P3(OMe)6-n(OC6H4Me-p)n (n = 4 or 5), yield dioxophosphaz-1-enes and an oxophosphazadiene respectively.The 1H, 13C and 31P NMR data for the starting materials and the products are presented.No evidence has been found for partially rearranged products.The geometrical disposition of the aryloxy groups in the starting material is retained in the rearranged products.Some aspects of the mechanism of the thermal rearrangement are discussed.
View MoreTriumph International Development Limilted
website:http://www.jiashengchem.cn/
Contact:+86-536-7971999
Address:Yinhai Road,Shouguang
Suzhou Jingye Medicine & Chemical Co., Ltd
Contact:+86-512-66658588
Address:No. 88, Sanlian Street, Jinfeng Road, Suzhou New District, Jiangsu Province, P. R. China
Jinan Boss Chemical Industry Co., Ltd.【revoke the business license】
website:http://www.chemboss.com.cn
Contact:+86-531-58591595
Address:No2.Hualong Road, Jinan, China
SPRING CHEMICAL INDUSTRY CO.,LTD
Contact:86-187-66672125
Address:linchi industry park.zouping
Contact:86-532-68629711 13780605697
Address:NO 220 YANAN 3 ROAD,(POST ADMINISTRATION BUILDING),QINGDAO,CHINA
Doi:10.1016/j.crci.2011.05.003
(2011)Doi:10.1055/s-2000-6231
(2000)Doi:10.1016/j.tetlet.2011.03.009
(2011)Doi:10.1016/S0040-4039(00)99070-1
(1985)Doi:10.1002/ardp.19683010706
(1968)Doi:10.1039/b004761i
(2000)
