Stereoselective Addition of Diphenylphosphine: meso- and rac-1,2-Diphenyl-1,2-bis(diphenylphosphino)ethane and their Group 6 Metal Tetracarbonyl Complexes. Crystal Structures of the Molybdenum Derivatives

DOI: 10.1039/DT9900003621

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3621 - 3627 (1990)

Update date:2022-08-04

Topics:

Authors:

Bookham, Jonathan L.

McFarlane, William

Thornton-Pett, Mark

Jones, Simon

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Article abstract of DOI:10.1039/DT9900003621

The addition of diphenylphosphine, PPh2H, to diphenylethyne in the presence of KOBu^t has been followed by 31P n.m.r. spectroscopy, and according to the reaction conditions can yield cis, (2) or trans, (3), 1,2-diphenyl(diphenylphosphino)ethene

Full text of DOI:10.1039/DT9900003621

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