Highly enantioselective aerobic oxidation of α-hydroxyphosphonates catalyzed by chiral vanadyl(V) methoxides bearing N-salicylidene-α- aminocarboxylates

DOI: 10.1021/ja060639o

Source and publish data:

Journal of the American Chemical Society p. 6308 - 6309 (2006)

Update date:2022-08-04

Topics: Aerobic Oxidation α-Hydroxyphosphonates

Authors:

Pawar, Vijay D.

Bettigeri, Sampada

Weng, Shiue-Shien

Kao, Jun-Qi

Chen, Chien-Tien

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Article abstract of DOI:10.1021/ja060639o

An unprecedented vanadyl(V) methoxide complex 4 derived from 3,5-dibromo-N-salicylidene-l-tert-leucinate enables highly enantioselective aerobic oxidations of α-hydroxyphosphonates at ambient temperature with selectivity factors ranging from 3 to >99. Cop

Full text of DOI:10.1021/ja060639o

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