TRIETHYLBORANE INDUCED PERFLUOROALKYLATION OF SILYL ENOL ETHERS OR GERMYL ENOL ETHERS WITH PERFLUOROALKYL IODIDES

DOI: 10.1016/S0040-4039(00)97073-4

Source and publish data:

Tetrahedron Letters p. 6391 - 6394 (1990)

Update date:2022-08-03

Topics:

Authors:

Miura, Katsukiyo

Taniguchi, Masahiko

Nozaki, Kyoko

Oshima, Koichiro

Utimoto, Kiitiro

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Article abstract of DOI:10.1016/S0040-4039(00)97073-4

Reaction of perfluoralkyl iodides with silyl enol ethers mediated by Et3B in the presence of a base provides perfluoroalkylated silyl enol ethers.Meanwhile, treatment of germyl enol ethers with perfluoroalkyl iodides affords α-perfluoroalkyl ketones in good yields.

Full text of DOI:10.1016/S0040-4039(00)97073-4

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