Angewandte Chemie - International Edition p. 10457 - 10460 (2011)
Update date:2022-08-04
Topics:
Bauer, Juergen
Braunschweig, Holger
Kraft, Katharina
Radacki, Krzysztof
A difficult break-up: Boron trifluoride was activated by oxidative addition to the transition-metal complex [(Cy3P)2Pt]. The product of this addition, trans-[(Cy3P)2Pt(BF2) (FBF3)], was characterized by NMR spectroscopy and crystal structure determination. Furthermore, the degradation product trans-[(Cy 3P)2Pt(H)(FBF3)] and the stable derivative trans-[(Cy3P)2Pt(BF2)(Cl)] were fully characterized. Copyright
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