Electrochemically Induced Nucleophilic Substitution of Perfluoroalkyl Halides. An Example of a Dissociative Electron-Transfer-Induced Chemical Reaction

DOI: 10.1021/ja00018a025

Source and publish data:

Journal of the American Chemical Society p. 6872 - 6879 (1991)

Update date:2022-07-30

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Authors:

Medebielle, Maurice

Pinson, Jean

Saveant, Jean-Michel

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Article abstract of DOI:10.1021/ja00018a025

Nucleophilic substitution of perfluoroalkyl halides can be induced electrochemically.The reaction mechanism is a slightly modified version of the classical S_RN1 mechanism in which the reaction is triggered by dissociative electron transfer, not

Full text of DOI:10.1021/ja00018a025

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