Palladium-catalyzed ene-type cyclizations of terpenoid 1,6-enynes

DOI: 10.1002/hlca.19910740308

Source and publish data:

Helvetica Chimica Acta p. 517 - 530 (1991)

Update date:2022-07-30

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Authors:

Knierzinger, Andreas

Grieder, Alfred

Schonholzer, Peter

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Article abstract of DOI:10.1002/hlca.19910740308

Palladium-catalyzed ene-type cyclizations of 1,6-enynes 2 yield methylidene-cyclopentane derivatives 3. Removal of protecting groups from 3 furnishes the diols 4 and 5, whose configurations were established by a combination of X-ray and ¹H-NMR

Full text of DOI:10.1002/hlca.19910740308

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