Chromium complexes supported by phenanthrene-imine derivative ligands: Synthesis, characterization and catalysis on isoprene cis-1,4 polymerization

DOI: 10.1039/c2dt11365a

Source and publish data:

Dalton Transactions p. 2755 - 2763 (2012)

Update date:2022-07-30

Topics:

Authors:

Gao, Bo Gao, Bo

Luo, Xuyang

Gao, Wei

Huang, Long

Gao, Si-Meng

Liu, Xiaoming

Wu, Qiaolin

Mu, Ying

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Article abstract of DOI:10.1039/c2dt11365a

Reactions of CrCl₂(THF)₂ with N-aryl-9,10- iminophenanthraquinone in CH₂Cl₂ give the monoimine chromium complexes ^ArIPQCrCl₂(THF)₂ (1, Ar = 2,6-Me₂C₆H₃

Full text of DOI:10.1039/c2dt11365a

Electronic Supplementary Material (ESI) for Dalton Transactions

This journal is © The Royal Society of Chemistry 2012

Cr2p Scan

5 Scans, 2 m 30.2 s, 500µm, CAE 30.0, 0.05 eV

1.50E+04

1.40E+04

1.30E+04

1.20E+04

1.10E+04

1.00E+04

9.00E+03

8.00E+03

7.00E+03

590

580

570

Binding Energy (eV)

SFigure 1. The XPS spectrum of complex 4.

SFigure 2. Stacked ¹H NMR of L1, L4, L6, and L7

Products guided by the article

Product name:C₃₄H₃₄N₂

Cas No:1354657-08-1

R&D Labs maybe for 1354657-08-1

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