Alkynylations of Oxiranes with Lithium Acetylides by the Catalysis of Trimethylgallium

DOI: 10.1246/bcsj.64.1810

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1810 - 1813 (1991)

Update date:2022-07-30

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Authors:

Fukuda, Yukitoshi

Matsubara, Seijiro

Lambert, Claude

Shiragami, Hiroshi

Nanko, Toshiki

et al. et al.

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Article abstract of DOI:10.1246/bcsj.64.1810

The reaction of 1-lithio-1-alkynes with oxiranes under the catalytic action of trimethylgallium afforded the corresponding β-hydroxy acetylenic compounds in good yields with excellent regioselectivities.No isomerization of oxiranes was observed during the

Full text of DOI:10.1246/bcsj.64.1810

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